关附辛素的结构鉴定
STRUCTURE OF GUANFU BASE H
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摘要: 常用中药关白附子为毛茛科黄花乌头Aconitum coreanum(LevL.)Raipaics的块根。曾报道从关白附子脂溶性部分分得次乌头碱和关附甲、乙、丙、丁、戊、己、庚素等生物碱,并确定了关附庚素和甲素的结构及绝对构型。本文所得水溶性生物碱一关附辛素经鉴定证明其结构与文献报道的atisinium chloride一致。Abstract: Guanfu base H was obtained from Aconitum coreanum (Levl.) Raipaics for the first time. It was identified as atisinium chloride using IR, PMR, CMR, MS.