Abstract:
Aim :The tandem Claisen rearrangement/Diels-Alder reaction in ionic liquid was carried out to find better changes for the conversion.
Methods :The synthesis started with replaced benzoic acid via acylation,cyclization,demethylation,allylation and then tandem Claisen rearrangement/Diels-Alder reaction in trational solvent and ionic liquid separately.
Results :BmimBF
4 raised the yield of the target compound and shortened the reaction time compared with the traditional solvent.
Conclusion :BmimBF
4 can promote the tandem Claisen rearrangement/Diels-Alder reaction.