Asymmetric Cyclization Using Rhodium(I)with Chiral Ligand

Asymmetric Cyclization Using Rhodium(I)with Chiral Ligand[J]. Journal of China Pharmaceutical University, 1995, (6): 324-328.

Citation:

Asymmetric Cyclization Using Rhodium(I)with Chiral Ligand[J]. Journal of China Pharmaceutical University, 1995, (6): 324-328.

Citation:

Asymmetric Cyclization Using Rhodium(I)with Chiral Ligand[J]. Journal of China Pharmaceutical University, 1995, (6): 324-328.

Abstract

Highly diastereoselective cyclization (> 99?) of 3R(or S)3,-disubetituted 4-pentenals into the corresponding 3,4-cis(or trans)-disubstituted cyclopentanone was achieved by using cationic RH (BINAP) ClO4 or neutral RhCl (BINAP).The asymmetric cyclization

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