- 中国精品科技期刊
- 中国高校百佳科技期刊
- 中国中文核心期刊
- 中国科学引文数据库核心期刊
| Citation: |
ZHANG Xinggui, FANG Siyang, CHEN Rui, et al. Volatile aromatic components and pyrolytic products in ethanol extracts of Cyclocarya paliurus by GC-MS[J]. J China Pharm Univ, 2024, 55(4): 493 − 503. DOI: 10.11665/j.issn.1000-5048.2023121501
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In order to investigate the feasibility of the extract from Cyclocarya paliurus as an additive in cigarettes, the volatile aromatic components were analyzed by gas chromatography-ion mobility spectrometry (GC-IMS), and C.paliurus extract was pyrolyzed to simulate cigarette smoking by TGA-GC/MS. The cracking products of C.paliurus were analyzed in a nitrogen environment, and the possible cracking mechanism of the products was reasonably speculated. The results showed that aldehydes, alcohols, and ketones were the primary volatile aroma components of the C.paliurus extract, comprising 62.28% of the total aroma components. The cracking products of C.paliurus extract varied greatly under different temperature conditions. A total of 79 compounds were identified at 200,360, and 440 ℃, among which 24 aromatic components were clearly identified as having significant effects on cigarette style, including aldehydes, ketones, alcohols, phenols, furans, benzene series, and other natural aromatic substances. Among them, phenols containing a high concentration are mainly formed by compounds containing the structure of guaiacol unit and eugenol unit by side chain cleavage, demethylation, demethoxylation, dehydration, etc. Furan and its derivatives are mainly formed by glycosides or glycoside compounds by breaking glucoside bonds and dehydration.
| [1] |
Chen ZL, Jian YQ, Wu Q, et al. Cyclocarya paliurus (batalin) iljinskaja: botany, ethnopharmacology, phytochemistry and pharmacology[J]. J Ethnopharmacol, 2022, 285 : 114912.
|
| [2] |
Zhang HY. The Chinese Traditional Medicine Resource (中国中药资源志要) Records. Beijing: Science Press, 1994: 159.
|
| [3] |
Shen YB, Peng Y, Zhu XC, et al. The phytochemicals and health benefits of Cyclocarya paliurus (Batalin) Iljinskaja[J]. Front Nutr, 2023, 10: 1158158. doi: 10.3389/fnut.2023.1158158
|
| [4] |
Wang H, Tang C, Gao ZZ, et al. Potential role of natural plant medicine Cyclocarya paliurus in the treatment of type 2 diabetes mellitus[J]. J Diabetes Res, 2021, 2021: 1655336.
|
| [5] |
Wang KP, Li WR, Song MZ, et al. Research progress on chemical constituents, biological activities and product development of Cyclocarya paliurus[J]. Chin J Hosp Pharm, 2023, 43(18): 2100-2104.
|
| [6] |
Wang J, Mao Y, Yang WY, et al. A preparation method of plant faint-scent cigarette: CN105077574B[P]. 2018-09-21.
|
| [7] |
Li GM. A kind of smoking cessation cigarettes-Cyclocarya paliurus cigarettes: CN104799427B[P]. 2017-01-11.
|
| [8] |
Liu H, Chu GL, Ren ZY, et al. Study on the moisturizing and flavor-increasing mechanism of polysaccharides and its application in cigarettes[J]. Food Ind (食品工业), 2022, 43(7): 39-44.
|
| [9] |
Zhu LJ, Cao Y, Qin YH, et al. Effect of glycerol addition ratio on thermal properties and pyrolysis products of tobacco sheet of heated cigarette[J]. Acta Tabacaria Sin (中国烟草学报), 2022, 28(5): 8-16.
|
| [10] |
Luo RC, Zhao ZY, Liu HG, et al. Effect of pyrolytic temperature of β-carotene on the pyrolytic products[J]. J Food Sci Biotechnol (食品与生物技术学报), 2003(3): 67-75.
|
| [11] |
Han Y, Yang Z, Zou XM, et al. Analysis of volatile components and thermal cracking products of Buxus fruit extract and its application in cigarettes[J]. Light Ind Sci Technol (轻工科技), 2021, 37(8): 4-7.
|
| [12] |
Zhang WL, Rong H, Zhao XD, et al. Pyrolysis Constituents of Elsholtzia bodineri Vaniot and effects of the same on deliveries of seven harmful components in mainstream cigarette smoke[J]. J Yunnan Agric Univ (云南农业大学学报), 2018, 33(6): 1105-1112.
|
| [13] |
Hai XC. Study on the characteristic flavor of caramel malt and its changing law in the roasting process (焦香麦芽特征风味及其在焙焦过程中变化规律研究) [D]. Yangzhou: Yangzhou University, 2019.
|
| [14] |
Guan TQ, Zhang B, Zhang L, et al. Analysis of pyrolysis products of Peru extract[J]. Light Ind Sci Technol (轻工科技), 2018, 34(2): 5-6,148.
|
| [15] |
Li C, Liu JY, Cai JY, et al. Analysis of aroma compounds in different flavored cigarette paper by using headspace-gas chromatography-ion mobility spectrometry[J]. J Light Ind (轻工学报), 2023, 38(2): 80-86.
|
| [16] |
Tian LM, Miao EM, Zeng WL, et al. Pyrolysis products analysis of honeysuckle by gas chromatography-mass spectrometer[J]. Chin Agric Sci Bull (中国农学通报), 2017, 33(5): 116-121.
|
| [17] |
Liu XG, Chen YS. Study on synthesis of 2-methyltetrafuran-3-one from ethyl lactate and methyl acrylate[J]. Food Sci (食品科学), 2005, 26(5): 165-167.
|
| [18] |
Wang B, Fan Z, Li HL, et al. Effect of ventilation on the release of typical phenolic flavor components in mainstream cigarette smoke[J]. J Light Ind (轻工学报), 2022, 37(4): 58-65.
|
| [19] |
Dai JG, Li YJ, Zhang P, et al. Study on the pyrolysis behavior of loquat leaf extract[J]. J Light Ind (轻工学报), 2015, 30(1): 30-35.
|
| [20] |
Zhu H, Chai GB, Chi GJ, et al. Sensory-oriented analysis of smoky components in mainstream cigarette smoke[J]. Tob Sci Technol (烟草科技), 2017, 50(1): 41-49.
|
| [21] |
Liao HY, Wu Y, Sun HP, et al. Analysis of methyleugenol in mainstream cigarette smoke by solid phase extractiondouble packing reverse extraction coupled with GC/MS[J]. Tob Sci Technol (烟草科技), 2021, 54(4): 66-73.
|
| [22] |
Wang HJ, Jing XY, Liu LF, et al. Analysis of volatile components in Pimenta dioica leaf oil and its application in cigarette[J]. J Henan Agric Sci (河南农业科学), 2013, 42(3): 143-145.
|
| [23] |
Chu GL. Analysis of pyrolytic properties of polysaccharides and its application in cigarette (多糖的热裂解性质分析及其在卷烟中的应用) [D]. Nanchang: Nanchang University, 2023.
|
| [24] |
Huang YC, Gong CR, Guo R, et al. Research progress on the relationship between pigment and aroma substances in flue-cured tobacco[J]. J Henan Agric Sci (河南农业科学), 2008, 37(2): 5-9.
|
| [25] |
Peng YX. Analysis of the characteristic aroma components of Hunan Fu brick tea (湖南茯砖茶特征香气成分分析) [D]. Tianjin: Tianjin University, 2022.
|
| [26] |
Chigo-Hernandez MM, Tomasino E. Aroma perception of limonene, linalool and α-terpineol combinations in pinot Gris wine[J]. Foods, 2023, 12(12): 2389. doi: 10.3390/foods12122389
|
| [27] |
Mei X, Xu JG, Su LL, et al. Rapid identification of odor difference markers before and after bran-fried Aurantii Fructus based on Heracles NEO ultra-fast gas phase electronic nose[J]. Chin Tradit Herb Drugs (中草药), 2023, 54(16): 5165-5171.
|
| [28] |
Kaur R, Tarun Kumar V, Krishna BB, et al. Characterization of slow pyrolysis products from three different cashew wastes[J]. Bioresour Technol, 2023, 376: 128859. doi: 10.1016/j.biortech.2023.128859
|
| [29] |
Lu XY, Gu XL. A review on lignin pyrolysis: pyrolytic behavior, mechanism, and relevant upgrading for improving process efficiency[J]. Biotechnol Biofuels Bioprod, 2022, 15(1): 106. doi: 10.1186/s13068-022-02203-0
|
| [30] |
Hu J, Shen DK, Xiao R, et al. Free-radical analysis on thermochemical transformation of lignin to phenolic compounds[J]. Energy Fuels, 2013, 27(1): 285-293. doi: 10.1021/ef3016602
|
| [31] |
Chen T, Qi XP, Chen MJ, et al. Gas chromatography-ion mobility spectrometry detection of odor fingerprint as markers of rapeseed oil refined grade[J]. J Anal Methods Chem, 2019, 2019: 3163204.
|
| [32] |
Hu X, Wang RR, Guo JJ, et al. Changes in the volatile components of candied kumquats in different processing methodologies with headspace-gas chromatography-ion mobility spectrometry[J]. Molecules, 2019, 24(17): 3053. doi: 10.3390/molecules24173053
|
| [33] |
Li WQ, Chen YP, Blank I, et al. GC × GC-TOF-MS and GC-IMS based volatile profile characterization of the Chinese dry-cured hams from different regions[J]. Food Res Int, 2021, 142: 110222. doi: 10.1016/j.foodres.2021.110222
|
| [34] |
Ma Y, Wang YY, Guan MR, et al. Changes of the color and odor of the flowers from Lonicera japonica in different development[J]. Chin Tradit Pat Med (中成药), 2019, 41(6): 1349-1353.
|
| [35] |
Chen WL. Base on chromatography-mass spectrometry technology research chemical constituents of Cyclocarya paliurus leaf (基于色谱-质谱技术研究青钱柳叶化学成分) [D]. Nanchang: Nanchang University, 2018.
|
| [36] |
Kou XL, Li TT, Wu CE, et al. Optimization of the extraction of the volatile substances in Cyclocarya paliurus tea based on GC-TOF-MS[J]. Mod Food Sci Technol (现代食品科技), 2019, 35(8): 261-270.
|
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